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dc.contributor.authorGolla, Sivaparwathi-
dc.contributor.authorPoshala, Soumya-
dc.contributor.authorPawar, Ravinder-
dc.contributor.authorKokatla, Hari Prasad-
dc.date.accessioned2025-10-23T05:19:59Z-
dc.date.available2025-10-23T05:19:59Z-
dc.date.issued2019-
dc.identifier.citation10.1016/j.tetlet.2019.151539en_US
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/3401-
dc.descriptionNITWen_US
dc.description.abstractA novel rongalite-promoted metal-free aerobic ipso-hydroxylation of arylboronic acids has been developed. This method employs low-cost rongalite as a radical initiator and O2 as a green oxidizing agent for ipso-hydroxylation. This protocol is compatible with a wide variety of functional groups with good to excellent yields at room temperature. Furthermore, mechanistic insight into the role of superoxide radical anions in C-B cleavage has also been provided based on DFT studies.en_US
dc.language.isoenen_US
dc.publisherTetrahedron Lettersen_US
dc.subjectAerobic oxidationen_US
dc.subjectArylboronic aciden_US
dc.subjectRongaliteen_US
dc.subjectSuperoxide radical anionen_US
dc.titleRongalite-promoted metal-free aerobic ipso-hydroxylation of arylboronic acids under sunlight: DFT mechanistic studiesen_US
dc.typeArticleen_US
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