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dc.contributor.authorBaruah, Arabinda-
dc.contributor.authorJha, Menaka-
dc.contributor.authorKumar, Santosh-
dc.contributor.authorGanguli, AshokKumar-
dc.date.accessioned2025-05-02T09:22:01Z-
dc.date.available2025-05-02T09:22:01Z-
dc.date.issued2015-
dc.identifier.citation10.1088/2053-1591/2/5/056404en_US
dc.identifier.urihttp://localhost:8080/xmlui/handle/123456789/3254-
dc.descriptionNITWen_US
dc.description.abstractFabricationofcontrolledlayeredstructuredthinfilmswithtunablephysicalpropertiesisanimportant areaofresearchasthinfilmtechnologyholdspotentialforavarietyofindustrialapplications.Inthe presentwork,wehavedemonstratedtheprocessforfabricationofmultilayerfilmsofsilicaand tantalumoxidebyLangmuir–Blodgettfilmfabricationtechniqueandinvestigatedtheirphotocatalytic degradationefficiencyfororganicdye(RhodamineB)underUVradiation.Thephotocatalytic degradationofRhBinpresenceofSiO2–Ta2O5exhibitedremarkablyenhancedphotocatalyticactivity thanpureTa2O5.Thisisbecauseofthehighseparationefficiencyofphoto-generatedelectron–hole pair duetotheLewisacidityofsilicaandthegreatercontactareabetweenthesetwolayers.TheSiO2Ta2O5systemwasoptimizedforthenumberofself-assembledlayersofsilicaandtantalumoxide,and it hasbeenfoundthat10S–15T–10S–15T–10S–15T(whereSandTrepresentsSiO2andTa2O5 respectively) pattern hasbeenfoundtohavemaximumphotocatalyticdegradationefficiencyof71% (with18%degradationperunitareaofthefilm)whichis3.5foldhigherthanpureTa2O5under identical experimental condition.Also,thephotocatalyticactivityofthesefilmswasalsoprovedtobe sensitive to thesequenceofsilicaandtantalumoxidelayerswhenthefilmareaofallthesampleswas keptconstant(3.75 cm2).Furtheranalysisconfirmsthatthedegradationofdyemoleculeshasbeen largely promotedbythephotogeneratedholes,ratherthanthesuperoxideradicalanions.en_US
dc.language.isoenen_US
dc.publisherMaterials Research Expressen_US
dc.subjectTantalum pentoxideen_US
dc.subjectSilicaen_US
dc.titleEnhancement of photocatalytic efficiency using heterostructured SiO2-Ta2O5 thin filmsen_US
dc.typeArticleen_US
Appears in Collections:Chemistry

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