Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/123456789/3155
Title: Efficient, Stereoselective Approach to the Synthesis of 3-(1-Phenyl-2-(Z-styrylsulfonyl)-1H-imidazol-4-yl)-2H-chromen-2-ones
Authors: Guravaiah, N.
Rao, V.R.
Keywords: 3-(2-Mercapto-1-phenyl-1H-imidazol-4-yl)-2H-chromen-2-ones
phenylacetylene
Issue Date: 2011
Publisher: Synthetic Communications An International Journal for Rapid Communication of Synthetic Organic
Citation: 10.1080/00397911003797874
Abstract: Reaction of phenyl acetylene with 3-(1-aryl-2-mercapto-4-imidazolyl)-2H-1-benzopyran-2-ones (4) in the presence of sodium hydroxide in absolute ethanol led to the formation of 3-(1-phenyl-2-(Z-styrylthio)-1H-imidazol-4-yl)-2H-chromen-2-ones (6) in excellent yields. These, on further oxidation with H2O2/AcOH, gave the corresponding sulfones (7) with retention of stereochemistry.
Description: NITW
URI: http://localhost:8080/xmlui/handle/123456789/3155
Appears in Collections:Chemistry



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