<?xml version="1.0" encoding="UTF-8"?>
<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns="http://purl.org/rss/1.0/" xmlns:dc="http://purl.org/dc/elements/1.1/">
  <channel rdf:about="http://localhost:8080/xmlui/handle/123456789/104">
    <title>DSpace Collection:</title>
    <link>http://localhost:8080/xmlui/handle/123456789/104</link>
    <description />
    <items>
      <rdf:Seq>
        <rdf:li rdf:resource="http://localhost:8080/xmlui/handle/123456789/3510" />
        <rdf:li rdf:resource="http://localhost:8080/xmlui/handle/123456789/3480" />
        <rdf:li rdf:resource="http://localhost:8080/xmlui/handle/123456789/3479" />
        <rdf:li rdf:resource="http://localhost:8080/xmlui/handle/123456789/3478" />
      </rdf:Seq>
    </items>
    <dc:date>2026-04-26T08:51:37Z</dc:date>
  </channel>
  <item rdf:about="http://localhost:8080/xmlui/handle/123456789/3510">
    <title>INVESTIGATIONS ON FLEXURAL RESPONSE OF FRC  BEAMS REINFORCED WITH BASALT FIBER REINFORCED  POLYMER REBARS</title>
    <link>http://localhost:8080/xmlui/handle/123456789/3510</link>
    <description>Title: INVESTIGATIONS ON FLEXURAL RESPONSE OF FRC  BEAMS REINFORCED WITH BASALT FIBER REINFORCED  POLYMER REBARS
Authors: SAGAR, BHANAVATH
Abstract: Investigations on the flexural response of fiber reinforced concrete (FRC) beams reinforced &#xD;
with basalt fiber reinforced polymer (BFRP) rebars are presented. The development of &#xD;
durability related issues in traditional steel reinforced concrete (RC) structures due to embedded &#xD;
steel reinforcement corrosion is the biggest problem that is causing the shortening of service &#xD;
life of the steel RC structures. Reinforcing the concrete structures using non-metallic and non&#xD;
corrosive fiber reinforced polymer (FRP) rebars will ensure that the structure remains &#xD;
corrosion-free. BFRP rebar is a newly developed FRP rebar that is emerging as a green &#xD;
construction material, and it has become one of the best alternatives to existing FRP rebars. All &#xD;
FRP rebars have a lower Young’s modulus and higher tensile strength than steel reinforcing &#xD;
bars. As a result, FRP reinforced plain concrete beams become less ductile, experience more &#xD;
deflections, and produce more cracks at higher flexural strengths. The flexural behaviour of &#xD;
steel or FRP RC beams not only depends on the area and type of reinforcement provided but &#xD;
also on the properties of the concrete used. The application of BFRP rebars in FRC can increase &#xD;
its performance as a longitudinal reinforcement, as the drawbacks associated with plain &#xD;
concrete (PC) beams reinforced with BFRP rebars can be decreased by increasing the strength &#xD;
and tensile properties of concrete with the addition of fibers. In this study, an attempt was made &#xD;
to develop an eco-friendly reinforcing system (BFRP rebars + basalt fibers and/or polyvinyl &#xD;
alcohol (PVA) fibers) to investigate the flexural response of BFRP reinforced basalt fiber &#xD;
reinforced concrete (BFRC) and PVA fiber reinforced concrete (PVAFRC) beams. Therefore, &#xD;
the present study was aimed to investigate the flexural response of PC, BFRC and PVAFRC &#xD;
beams reinforced with BFRP rebars. This investigation was carried out using two concrete &#xD;
grades: normal strength concrete (NSC) of M30 grade and high strength concrete (HSC) of &#xD;
M70 grade. &#xD;
The use of pozzolanic materials in concrete manufacturing provides economical, technological, &#xD;
and environmental benefits. In this study, alccofine-1203 and fly ash were used as &#xD;
supplementary cementitious materials (SCMs) to partially replace cement in the development &#xD;
of HSC. 4%, 6%, 8%, 10%, 12% and 14% alccofine-1203 with 20% fly ash combination were &#xD;
used to partially replace cement to find the optimum percentage of alccofine-1203 to be used &#xD;
in the development of HSC. For this, a total of seven binder proportions were prepared and &#xD;
evaluated for mechanical properties, microstructural characteristics and compressive stress&#xD;
strain behavior. From the obtained results, it was found that the use of alccofine-1203 in &#xD;
combination with fly ash was beneficial in the development of HSC. Among all, the &#xD;
i &#xD;
replacement of cement with 10% alccofine-1203 with a 20% fly ash combination attributed &#xD;
superior microstructural characteristics for binder mixes and showed highest mechanical &#xD;
properties and compressive stress-strain behaviour for the concrete.  &#xD;
In this study, to improve the flexural performance of BFRP RC beams, BFRC was developed &#xD;
using basalt fibers and PVAFRC was developed using PVA fibers. To determine the optimum &#xD;
percentage of basalt fibers and PVA fibers to use for manufacturing BFRC and PVAFRC, &#xD;
additions of 0.1%, 0.2%, 0.3%, 0.4%, and 0.5% (of the volume of concrete) basalt fibers and &#xD;
PVA fibers were made to the developed NSC and HSC. Consequently, a total of 20 mixes (10 &#xD;
BFRC mixes and 10 PVAFRC mixes) were developed and evaluated for fresh and hardened &#xD;
properties. The workability, compressive strength, flexural strength, split tensile strength, load&#xD;
deflection behaviour, and uniaxial compressive stress-strain behaviour of BFRCs and &#xD;
PVAFRCs were studied experimentally. Young’s modulus, and energy absorption capacity, &#xD;
peak-stress, and strain at peak-stress of BFRCs and PVAFRCs have also been studied &#xD;
analytically. Scanning electron microscopy analysis was performed to examine microstructural &#xD;
characteristics of BFRCs and PVAFRCs. The results indicated that the addition of basalt or &#xD;
PVA fibers reduced the workability of concrete mixes. The maximum compressive strength, &#xD;
flexural strength, split tensile strength and better load-deflection and stress-strain behaviour &#xD;
were obtained with the addition of 0.3% of basalt fibers in two strengths of BFRCs and 0.3% &#xD;
PVA fibers in two strengths of PVAFRCs. The modified constitutive analytical model and &#xD;
relationships between properties of compressive stress-strain curves of BFRCs and PVAFCs &#xD;
such as peak-stress, strain at peak stress and material parameter (𝛽𝑛) with modified reinforcing &#xD;
index values of fibbers were proposed for analytical modelling of stress-strain curves of BFRCs &#xD;
and PVAFRCs of two strengths, and a good agreement with experimental results was observed. &#xD;
Additionally, in the literature, the proposed constitutive analytical model and relationships &#xD;
between the material parameter and reinforcing index for analytical modelling of FRC’s stress&#xD;
strain curves failed to accurately predict the experimental stress-strain curves of BFRCs and &#xD;
PVAFRCs. &#xD;
To test the flexural response of BFRP RC (PC, BFRC, and PVAFRC) beams, 16 single&#xD;
reinforced concrete beams with a pure bending region were cast and tested experimentally. &#xD;
Twelve beams were longitudinally reinforced with BFRP rebars in the tension region and four &#xD;
beams were fully reinforced with steel reinforcing bars. Two grades of concrete- NSC and HSC; &#xD;
two types of FRC- BFRC and PVAFRC; and two types of RC sections- under-reinforced and &#xD;
over-reinforced were parameters considered in the investigation. All the beams were tested for &#xD;
ii &#xD;
load-deflection behaviour, moment-curvature relationships, ductility, cracking pattern and &#xD;
failure mode evaluation. The optimum percentage of basalt fibbers and PVA fibers (0.3%) was &#xD;
taken to prepare BFRC and PVAFRC. The obtained results showed that the load-deflection and &#xD;
moment-curvature response of BFRP-reinforced PC, BFRC, and PVAFRC beams exhibited &#xD;
two phases which bounded the cracking point, whereas steel-reinforced PC beams exhibited &#xD;
three phases which bound the cracking and yielding points. Although BFRP rebar is a brittle &#xD;
material with no clear yielding point, BFRP RC beams exhibited more deformation and &#xD;
curvature prior to failure during testing. The amount of deflection, curvature, stiffness and &#xD;
ductility that were exhibited by BFRP-reinforced PC beams were partially countered by &#xD;
reinforcing PC with basalt fibers and PVA fibers. However, due to the higher bond strength and &#xD;
better strain softening behaviour, PVA fibers improved flexural behaviour of BFRP RC beam &#xD;
better than the basalt fibers. &#xD;
ABAQUS based non-linear finite element numerical modelling was conducted to validate the &#xD;
experimental results of BFRP-reinforced PC, BFRC, and PVAFRC beams. The investigation &#xD;
parameters considered in experimental evaluation were the same as those considered in &#xD;
numerical modelling. All the numerically modelled beams were evaluated for load-deflection &#xD;
behaviour, moment-curvature response, ductility and damage pattern. The results showed that &#xD;
the numerical modelled beams behaved similar to the experimentally tested beams. The &#xD;
percentage of error between experimental and numerical results was found within 10%. This &#xD;
shows good agreement between them. The numerically modelled beams accurately illustrated &#xD;
concrete damage in compression and tension, as well as a cracking pattern in tension, in a &#xD;
manner similar to that of the experimental cracking and the damage patterns of concrete in &#xD;
compression and tension. &#xD;
iii
Description: NITW</description>
    <dc:date>2023-01-01T00:00:00Z</dc:date>
  </item>
  <item rdf:about="http://localhost:8080/xmlui/handle/123456789/3480">
    <title>AN EXPERIMENTAL INVESTIGATION ON THE ENGINEERING  BEHAVIOUR OF CHEMICALLY STABILISED EXPANSIVE SOILS</title>
    <link>http://localhost:8080/xmlui/handle/123456789/3480</link>
    <description>Title: AN EXPERIMENTAL INVESTIGATION ON THE ENGINEERING  BEHAVIOUR OF CHEMICALLY STABILISED EXPANSIVE SOILS
Authors: Ramanjaneya Raju, E.
Abstract: Expansive soils are popularly known in India as black cotton soils. They have an inherent &#xD;
nature to experience changes in volume depending upon changes in water content. Hence, they &#xD;
heave or increase in their volume when they absorb water in rainy seasons and shrink or &#xD;
decrease in their volume when they lose water on evaporation in summer seasons. This &#xD;
propensity of expansive soils to respond to changes in water content makes them highly &#xD;
problematic. Owing to this alternate swelling and shrinkage, lightly loaded infrastructure like &#xD;
residential buildings, canal linings and pavements constructed upon them are damaged. &#xD;
Structural members such as flooring, walls and columns develop severe cracking. Diagonal &#xD;
tension cracks are observed above doors and windows and below window-sills in the case of &#xD;
lightly loaded buildings. &#xD;
To control these volume expansions and volume reductions of these soils, innovative foundation &#xD;
techniques have been invented.  The broad classification of these techniques is as follows: i) &#xD;
mechanical modification (Sand cushion and CNS layer), ii) physical modification, iii) chemical &#xD;
modification and iv) foundations counteracting tension. &#xD;
In mechanical modification, the top few layers of the expansive clay layer are removed and &#xD;
replaced by layers of non-expansive material such as sand and gravel. Sand cushion is a classic &#xD;
example of mechanical modification. Cohesive non-swelling (CNS) layer technique is another &#xD;
example of mechanical modification. In physical modification, the top layers of the soil stratum &#xD;
are excavated, pulverised and mixed with non-expansive materials like sands and gravels and &#xD;
compacted back in layers. As the soil layers are replaced by non-swelling materials, swelling is &#xD;
reduced. &#xD;
Foundations counteracting tension are special foundation techniques. The examples are under&#xD;
reamed piles, large-bottomed piers or belled piers, straight-shafted piers or drilled piers, and &#xD;
granular pile-anchors (GPAs). The swelling pressure of the soil causes the uplift force on these &#xD;
foundations. And skin friction causes the force resisting this uplift. Granular pile-anchors &#xD;
(GPAs) are a recent innovation over conventional granular piles. In a GPA, an anchor is &#xD;
created for the foundation using a mild steel anchor rod and a mild steel anchor plate placed at &#xD;
the bottom of the granular pile. When the expansive clay bed swells by imbibing water, &#xD;
swelling pressure uplifts the foundation. But, the anchorage in the GPA develops resistance to &#xD;
this uplift which is mobilised over the cylindrical GPA-clay interface. The resistance &#xD;
mobilised acts in the downward direction; and this resistance can be attributed to the weight of &#xD;
the GPA and the GPA-clay interface shear parameters, namely, c’ and φ’. &#xD;
In chemical modification, various chemicals and industrial byproducts such as lime, silica fume &#xD;
(SF), fly ash (FA), cement, rice husk ash (RHA), pond ash (PA), calcium chloride (CaCl2) and &#xD;
GGBS are added to expansive clay for controlling their volume changes, reducing their &#xD;
plasticity and improving their engineering behaviour. Chemical stabilisation of expansive clays &#xD;
basically works through flocculation and cementation which are the two important reactions of &#xD;
which one is an immediate reaction and the other is a time-bound reaction. Flocculation reduces &#xD;
plasticity and swelling. And cementation causes cementitious products which harden the blends. &#xD;
This thesis is a focused research on chemical stabilisation of a remoulded expansive clay. Lime, &#xD;
cement, fly ash and GGBS were used as the additives to the clay. Free swell index (FSI), liquid &#xD;
limit (LL), plastic limit (PL) and plasticity index (PI) were the index properties determined at &#xD;
varied amounts of the above additives. Compaction characteristics, hydraulic conductivity, &#xD;
unconfined compressive strength corresponding to varied curing periods and soaked CBR were &#xD;
the engineering properties studied. Further, to study the load-settlement characteristics, plate &#xD;
load tests were performed on clay beds stabilised with varied amounts of the above additives. &#xD;
Moreover, in another series of tests, the plain clay bed and the clay beds stabilised with 6% &#xD;
lime, 20% cement, 20% fly ash and 20% GGBS were subjected to five swell-shrink cycles. In &#xD;
each of the swell-shrink cycles, swelling was observed for 10 days and shrinkage was observed &#xD;
for 50 days. Thus, each clay bed was continuously monitored for 300 days for swelling and &#xD;
shrinkage. &#xD;
Furthermore, shrinkage/desiccation cracks developed in the untreated and the treated clay &#xD;
specimens were quantified by image analysis to determine the crack area, the crack density &#xD;
factor and the crack intensity factor.
Description: NITW</description>
    <dc:date>2024-01-01T00:00:00Z</dc:date>
  </item>
  <item rdf:about="http://localhost:8080/xmlui/handle/123456789/3479">
    <title>ASSESSMENT OF RAIL TRANSPORT NOISE  PERCEIVED BY TRACKSIDE DWELLERS</title>
    <link>http://localhost:8080/xmlui/handle/123456789/3479</link>
    <description>Title: ASSESSMENT OF RAIL TRANSPORT NOISE  PERCEIVED BY TRACKSIDE DWELLERS
Authors: SUDHIR KUMAR, BODDU
Abstract: Unplanned urbanization has led to the settlement of migrants from rural areas close to railway lines, &#xD;
exposing them to the continuous noise levels from the moving trains. These high, intense noise levels &#xD;
annoy and adversely affect the health of individuals living near railway lines. Every ambient noise &#xD;
study employs the source-path-receiver structure to explore the overall behavior of sound. Therefore, &#xD;
noise control techniques are necessary to modify the noise source mechanism, transmission path &#xD;
characteristics, and receiver perception. Among these techniques, eliminating railway noise at the &#xD;
source is the most effective method for mitigating noise. This study evaluated different train types, &#xD;
including various speeds and lengths, to determine their correlation with noise levels. Results &#xD;
showed that train speed had the strongest correlation with noise levels, the driving factor for &#xD;
maximum noise levels. When the train speed increases by 10 km/h, noise levels rise by 2.8 to 3 dBA. &#xD;
In the case of freight trains, the train length is a key parameter in the emission of railway noise when &#xD;
compared to passenger trains. The study also identified the type of trains with the highest noise &#xD;
levels, and a detailed examination of the mechanism responsible for this phenomenon was carried &#xD;
out. Multiple linear regression models for maximum and equivalent noise levels were developed for &#xD;
passenger and freight trains. In addition to source parameters, the current study evaluates a noise &#xD;
pollution hotspot: a railway-level crossing, where several activities related to transportation noise &#xD;
were involved. Train honking, train movement, road vehicles, and pedestrians contribute to the noise &#xD;
level at a railway-level crossing. Train horns are generally blown as trains approach railway level &#xD;
crossings and are mandatorily used to alert road users. However, the train horns are considered a &#xD;
nuisance to the nearby residents. A comprehensive noise monitoring survey was conducted at an &#xD;
access-controlled level crossing. Further, an Artificial Neural Network (ANN) based railway noise &#xD;
prediction model was developed to forecast maximum (Lmax) and equivalent (Leq) noise levels. &#xD;
Results revealed that train horns produced impulsive sound signals that fall under high-frequency &#xD;
one-third octave bands, causing severe irritation to trackside inhabitants. &#xD;
Noise levels are affected by changes in distance, intervening barriers, and atmospheric conditions &#xD;
along the transmission path between the source and the receiver. This study explored the variance &#xD;
of railway noise in an urban setting over various measuring distances, including 25, 50, 100, and &#xD;
200 m, with variables such as air temperature, humidity, and wind conditions. Results showed that &#xD;
the effect of the wind was more significant for larger distances between the source and the receiver. &#xD;
For every 1 m/s increase in wind speed within a distance of 50 m, the average sound attenuation &#xD;
induced by the upwind phenomena was 0.2 dBA. The impact of air temperature changes on received &#xD;
xx &#xD;
sound level from a moving source was insignificant within the range of temperatures considered in &#xD;
the study. The effect of humidity was observed to be less at shorter distances but at larger distances, &#xD;
increasingly attenuates noise levels.  &#xD;
Along the transmission path, the presence of a wall between the source and receiver can act as a &#xD;
noise barrier resulting in a reduction in intensity of noise. In urban areas, railway boundary walls are &#xD;
constructed to prevent encroachments of railway lands and to avoid pedestrians trespassing the &#xD;
railway tracks. This study aims to evaluate the effectiveness of such a boundary wall in reducing &#xD;
noise and proposes an improved alternative through Computational Fluid Dynamics (CFD) &#xD;
simulations. Various noise barriers with different geometry, shape, and surface materials were &#xD;
simulated and verified through field study measurements. Noise attenuation was evaluated by &#xD;
measuring railway noise spectra at different positions, including 0.5 m in front and behind the barrier &#xD;
and at the facade of the residential area. Results showed that as barrier height increased, insertion &#xD;
loss also increased, with a maximum attenuation of 17 dBA achieved with a rectangular barrier of &#xD;
height 6 m. The most effective noise barrier for reducing railway noise was a T-shaped barrier with &#xD;
a height of 6 m and a projection length of 2 m, with an insertion loss of 22 dBA. This study &#xD;
recommends constructing the barrier with soft materials on its surface to reflect and absorb sound &#xD;
waves effectively. &#xD;
In the last phase of this study, the impact of railway noise on the residents living along the railway &#xD;
line at several distances was assessed by measuring the noise inside houses. Additionally, a human &#xD;
perception survey was conducted to investigate the relationship between noise levels and annoyance &#xD;
during daily activities such as working, resting, conversing, eating, talking on the phone, and &#xD;
reading. Structural Equation Models (SEM) were employed to analyze the complex relationships &#xD;
between annoyance, disturbance, and health effects. The outcomes of this study reveal that both &#xD;
passenger and freight trains exceeded the permissible noise limits, with an excess of 36.8% and 15% &#xD;
during daytime and 75.15% and 41.8% during nighttime, respectively. The primary factors &#xD;
contributing to annoyance were identified as the source type and location of noise exposure. The &#xD;
annoyance levels associated with the time of noise exposure negatively impacted disturbances to &#xD;
daily activities and subsequent health effects. This phenomenon suggests a psychological adaptation &#xD;
known as habituation, where residents along railway lines gradually become accustomed to the noise &#xD;
over time. Furthermore, the cumulative impact of disturbances to daily activities can indirectly &#xD;
influence long-term health. Proximity to the railway line amplifies the relationship between &#xD;
annoyance and health effects.
Description: NITW</description>
    <dc:date>2024-01-01T00:00:00Z</dc:date>
  </item>
  <item rdf:about="http://localhost:8080/xmlui/handle/123456789/3478">
    <title>BEHAVIOUR OF PESTICIDES IN AGRICULTURAL  SOILS: ASSESSMENT AND BIOCHAR-BASED  CONTROL APPROACH</title>
    <link>http://localhost:8080/xmlui/handle/123456789/3478</link>
    <description>Title: BEHAVIOUR OF PESTICIDES IN AGRICULTURAL  SOILS: ASSESSMENT AND BIOCHAR-BASED  CONTROL APPROACH
Authors: MAJEE, PRASANTA
Abstract: The World Health Organization defines pesticides as chemical substances used to prevent, &#xD;
destroy, or mitigate pests, including vectors of disease and unwanted species harmful to food &#xD;
production and other commodities. While pesticides are crucial in modern agriculture for &#xD;
protecting crops and enhancing food production, their overuse can harm human health, the &#xD;
environment, and non-target species. Pesticide use raises environmental risks, especially &#xD;
regarding groundwater and surface water contamination. This necessitates a thorough &#xD;
understanding of pesticide behaviour in agricultural lands to address human health and &#xD;
environmental sustainability. Sorption characteristics of organic chemicals vary with location, &#xD;
influenced by factors like clay content, organic matter, and microbial presence. Understanding &#xD;
these characteristics is vital for developing effective remediation measures and pesticide &#xD;
management strategies. &#xD;
In the specific context of Telangana state, where pesticide usage has increased dramatically in &#xD;
recent years, there is a heightened risk of groundwater contamination with persistent organic &#xD;
pollutants. Imidacloprid and Atrazine are the two majorly used pesticides in this region. &#xD;
Therefore, this research aims to investigate the sorption, desorption, and leachability of widely &#xD;
used pesticides in the black cotton soils and red soil of the Telangana region. The objective is &#xD;
to provide a comprehensive assessment of the potential risks associated with groundwater &#xD;
pollution from these pesticides, offering valuable insights for tailored environmental &#xD;
management. &#xD;
Additionally, the study seeks to explore the efficacy of biochar derived from locally available &#xD;
cotton stalks in enhancing pesticide sorption. This aspect of the research is essential for &#xD;
developing targeted remedial measures against pesticide pollution and implementing effective &#xD;
pesticide management practices specifically tailored to the unique characteristics of the &#xD;
Telangana region. By shedding light on the sorption, desorption, and leaching behaviour of &#xD;
Imidacloprid and Atrazine, this research aims to empower policymakers with the knowledge &#xD;
necessary to formulate targeted strategies for environmental conservation and sustainable &#xD;
agricultural practices, thereby ensuring a harmonious balance between agricultural productivity &#xD;
and environmental preservation. &#xD;
vii &#xD;
The first phase of the study assesses the sorption desorption behaviour of insecticide &#xD;
Imidacloprid and herbicide Atrazine in four different agricultural soils (BC-1, BC-2, BC-3, RS) &#xD;
of Telangana region. The study reported that both the pesticides were weakly sorbed on the &#xD;
investigated soils. The sorption kinetics for both the pesticides were observed to occur in two &#xD;
stages- the quick initial adsorption stage, where 90% of the pesticide’s adsorption capacity &#xD;
reached within first few hours due to the rapid filling of empty spaces in soil particles, and the &#xD;
slow equilibrium stage.  Pseudo second order kinetic model demonstrated the best fit to the &#xD;
experimental data. Analysis of isotherm models indicated that the Freundlich isotherm model &#xD;
provided the best fit compared to Langmuir or Temkin isotherm models. Among the soil &#xD;
samples, BC-2 soil exhibited the highest Freundlich coefficient value (Kf), followed by BC-3, &#xD;
BC-1, and red soil. A strong positive correlation (r&gt;0.9) was observed between clay content and &#xD;
the Kf value, indicating that clay content significantly influences Imidacloprid adsorption to the &#xD;
soil. Interestingly, despite having a higher organic carbon content (0.57%), red soil showed a &#xD;
lower affinity for Imidacloprid compared to other soils, possibly due to the relatively low &#xD;
quantity of organic carbon present. Both temperature and pH exert significant influences on the &#xD;
sorption behaviour of Imidacloprid in the examined soils. As temperature rises, the sorption of &#xD;
Imidacloprid decreases, possibly due to increased solubility at higher temperatures. &#xD;
Additionally, lower pH levels demonstrate favourable conditions for sorption, as they facilitate &#xD;
the protonation of the solution, thereby increasing the cationic charge of the pesticide &#xD;
molecules. &#xD;
The second phase of the study focused on the degradation of Imidacloprid and Atrazine in soil &#xD;
to assess their persistence. The study reported that the half-life of Imidacloprid ranged from 67 &#xD;
to 83 days in the investigated soils, whereas the half-life of Atrazine ranged from 44 to 57 days. &#xD;
Imidacloprid showed greater persistence in the investigated soils compared to Atrazine. The &#xD;
Groundwater Ubiquity Score (GUS) index is employed to evaluate the leachability of pesticides &#xD;
in the soils under investigation. This screening method utilizes the KOC value and half-life (T1/2, &#xD;
days) of pesticides to assess the probability of groundwater contamination. The GUS values for &#xD;
Imidacloprid ranged from 2.25 to 2.62 in black cotton soils, while in red soil, it was reported as &#xD;
3.72. For Atrazine, GUS values ranged from 2.01 to 2.41 in black cotton soils, and in red soil, &#xD;
it was 3.16. GUS values falling between 1.8 and 2.8 in all black cotton soils suggest that both &#xD;
pesticides fall into the potentially mobile category. However, in red soil, where the values &#xD;
exceeded 2.8 for both pesticides, they are considered highly mobile. The results of the soil &#xD;
column leaching study corroborated these findings, as both Imidacloprid and Atrazine were &#xD;
viii &#xD;
detected in the leachate sample and migrated to the deeper sections of the column. The presence &#xD;
of pesticides in the deeper layer of the soil matrix could make the pesticides more persistent &#xD;
due to the absence of microorganisms, ultimately leading to groundwater contamination. &#xD;
The final phase of the study investigated the efficacy of cotton stalk biochar as soil amendments &#xD;
to improve pesticide sorption capacity in soils and reduce the mobility. The results indicate that &#xD;
the introduction of 0.5% and 1% cotton biochar (CBC) into the soil significantly enhanced the &#xD;
Kf values of Imidacloprid and Atrazine sorption across all the examined soils. The improved &#xD;
sorption capacity is a direct outcome of the augmented surface area and additional sorption sites &#xD;
resulting from the addition of CBC to the soil. Pesticide degradation study in biochar amended &#xD;
soils revealed that the addition of biochar to the soil had a slight effect on the half-life of &#xD;
Imidacloprid and Atrazine, with all cases showing a modest increase. With the incorporation of &#xD;
biochar, GUS values notably declined, falling below the threshold of 1.8 suggests a significant &#xD;
reduction in the mobility of both Imidacloprid and Atrazine within the investigated soils. The &#xD;
soil column leaching study revealed that biochar amended soil can retain pesticides in the top &#xD;
layers of the soil matrix for both Imidacloprid and Atrazine. &#xD;
Overall, it can be concluded from the findings of the present study that the sorption capacity of &#xD;
both Imidacloprid and Atrazine was notably low in all three black cotton soils and red soil. Clay &#xD;
content, temperature and pH was identified as the primary factor influencing pesticide sorption, &#xD;
while soil organic matter showed a negative correlation with the sorption coefficient due to its &#xD;
limited availability in the soil. Imidacloprid's prolonged half-life compared to Atrazine indicates &#xD;
its greater persistence in all investigated soils. The calculated GUS value categorized both &#xD;
Atrazine and Imidacloprid as falling within the highly mobile to mobile category, highlighting &#xD;
the region’s vulnerability to groundwater contamination from pesticides. The study underscored &#xD;
the high susceptibility of groundwater in this specific area of the Telangana region to &#xD;
contamination, emphasizing the urgent need for proactive measures to prevent potential &#xD;
catastrophes. The incorporation of cotton stalk biochar into the soils emerged as a promising &#xD;
strategy to mitigate the leaching potential of both pesticides, offering a potential solution to &#xD;
reduce environmental risks associated with pesticide use.
Description: NITW</description>
    <dc:date>2024-01-01T00:00:00Z</dc:date>
  </item>
</rdf:RDF>

